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Volumetric Analysis of Metal Finishing Solutions

By Andrew K McFadyen

Methods.


Aluminium Anodising and pretreatment.
02.01 Anodising (sulphuric acid type- free sulphuric acid)
02.02 Anodising (sulphuric acid type- total sulphuric acid)
02.03 Anodising (sulphuric acid type- aluminium - method 1)
02.04 Anodising (sulphuric acid type- aluminium - method 2)
02.05 Anodising (sulphuric acid type- chloride)
02.06 Anodising (oxalic acid type-oxalic acid)
02.07 Anodising (oxalic-sulphuric type- oxalic acid)
02.08 Anodising (oxalic-sulphuric type- total sulphuric acid)
02.09 Anodising (oxalic-sulphuric type-free sulphuric acid)
02.10 Anodising (chromic acid type-chromium trioxide - method 1)
02.11 Anodising (chromic acid type-chromium trioxide - method 2)
02.12 Anodising (chromic acid type-sulphate)
02.13 Anodising (chromic acid type-chloride)
02.14 Aluminium (alkaline etches- aluminium in alkaline etch)
02.15 Aluminium (anodising sealing solutions-nickel)
Electroplating and Electroless Plating Solutions
03.01 Brass (copper-zinc alloy-copper)
03.02 Brass (copper-zinc alloy-zinc)
03.03 Brass (copper-zinc alloy-free cyanide)
03.04 Brass (copper-zinc alloy- carbonate)
03.05 Brass (copper-zinc alloy- sodium sulphite)
04.01 Bronze (copper-tin alloy- copper)
04.02 Bronze (copper-tin alloy- tin)
04.03 Bronze (copper-tin alloy- free cyanide)
04.04 Bronze (copper-tin alloy- free sodium hydroxide)
04.05 Bronze (copper-tin alloy- sodium carbonate)
05.01 Cadmium (cyanide type- cadmium - method 1)
05.02 Cadmium (cyanide type- cadmium - method 2)
05.03 Cadmium (cyanide type- total sodium cyanide)
05.04 Cadmium (cyanide type- sodium hydroxide)
05.05 Cadmium (cyanide type- sodium carbonate)
06.01 Chromium (hexavalent type- chromium trioxide)
06.02 Chromium (hexavalent type- trivalent chromium)
06.03 Chromium (hexavalent type- sulphuric acid- method 1)
06.04 Chromium (hexavalent type- sulphuric acid- method 2)
06.05 Chromium (hexavalent type- fluoride, silicofluoride)
06.06 Chromium (hexavalent type- mixed oxides)
06.07 Chromium (hexavalent type- iron)
07.01 Copper (acid sulphate type- copper-method 1)
07.02 Copper (acid sulphate type- copper - method 2)
07.03 Copper (acid sulphate type- sulphuric acid)
07.04 Copper (acid sulphate type- chloride -gravimetric)
07.05 Copper (acid sulphate type- iron - gravimetric)
07.06 Copper (cyanide type- copper)
07.07 Copper (cyanide type- free cyanide)
07.08 Copper (cyanide type- carbonate)
07.09 Copper (cyanide type- hydroxide)
07.10 Copper (cyanide type- potassium sodium tartrate)
07.11 Copper (pyrophosphate type- copper)
07.12 Copper (pyrophosphate type- total pyrophosphate)
07.13 Copper (fluoborate type- copper)
07.14 Copper (fluoborate type- free fluoboric acid)
07.15 Copper (electroless- copper)
07.16 Copper (electroless- formaldehyde)
08.01 Gold (cyanide type- gold - method 1 - gravimetric)
08.02 Gold (cyanide type- gold - method 2 - gravimetric)
08.03 Gold (cyanide type- gold - method 3)
08.04 Gold (cyanide type- free potassium cyanide)
08.05 Gold (cyanide type- potassium carbonate)
08.06 Gold (cyanide type- copper)
09.01 Lead (fluoborate type- lead)
09.02 Lead (fluoborate type- free fluoboric acid)
10.01 Nickel solutions (Watts type- nickel sulphate)
10.02 Nickel solutions (Watts type- nickel chloride)
10.03 Nickel solutions (Watts type- boric acid)
10.04 Nickel (sulphamate type- nickel sulphamate)
10.05 Nickel (sulphamate type- nickel chloride)
10.06 Nickel (sulphamate type- boric acid)
10.07 Nickel strike (acid sulphate type- nickel sulphate)
10.08 Nickel strike (acid sulphate type- sulphuric acid)
10.09 Nickel strike (acid chloride type- nickel chloride)
10.10 Nickel strike (acid chloride type- hydrochloric acid - method 1)
10.11 Nickel strike (acid chloride type- hydrochloric acid - method 2)
10.12 Nickel (autocatalytic/electroless, hypophosphite type- nickel)
10.13 Nickel (electroless/autocatalytic hypophosphite type- sodium hypophosphite- method 1)
10.14 Nickel (electroless/autocatalytic hypophosphite type- sodium hypophosphite- method 2)
10.15 Nickel (electroless/autocatalytic hypophosphite type-sodium phosphite)
10.16 Cobalt-nickel solutions- nickel
10.17 Cobalt-nickel solutions- cobalt
11.01 Palladium nickel alloy- nickel .
11.02 Palladium- palladium
12.01 Silver (cyanide type- silver - method 1)
12.02 Silver (cyanide type- silver - method 2)
12.03 Silver (cyanide type- free cyanide)
12.04 Silver (cyanide type- carbonate)
12.05 Silver (cyanide type- hydroxide)
12.06 Silver (cyanide type- copper)
13.01 Tin (acid sulphate type- stannous tin)
13.02 Tin (acid sulphate type- total tin)
13.03 Tin (acid sulphate type- free sulphuric acid)
13.04 Tin (acid fluoborate type- stannous tin)
13.05 Tin (acid fluoborate type- fluoboric acid)
13.06 Tin (alkaline stannate type- tin [stannate])
13.07 Tin (alkaline stannate type- free hydroxide)
13.08 Tin (alkaline stannate type- sodium carbonate)
14.01 Tin-lead (fluoborate type- stannous tin)
14.02 Tin-lead (fluoborate type- lead - method 1)
14.03 Tin-lead (fluoborate type- lead - method 2)
14.04 Tin-lead (fluoborate type- free fluoboric acid)
14.05 Tin-lead (fluoborate type- total tin)
14.06 Tin-lead (methane sulphonic acid type- stannous tin)
14.07 Tin-lead (methane sulphonic acid type- total tin)
14.08 Tin-lead (methane sulphonic acid type- lead - method 1)
14.09 Tin-lead (methane sulphonic acid type- lead - method 2)
14.10 Tin-lead (methane sulphonic acid type- free methane sulphonic acid)
15.01 Tin-nickel alloy- stannous tin
15.02 Tin-nickel alloy- total tin
15.03 Tin-nickel alloy- nickel
15.04 Tin-nickel alloy- total chloride
15.05 Tin-nickel alloy- fluoride
16.01 Tin-zinc alloy (cyanide type- stannous tin)
16.02 Tin-zinc alloy (cyanide type- zinc)
16.03 Tin-zinc alloy (cyanide type- total cyanide)
16.04 Tin-zinc alloy (cyanide type- total hydroxide)
17.01 Zinc (cyanide type- zinc - method 1)
17.02 Zinc (cyanide type- zinc - method 2)
17.03 Zinc (cyanide type- zinc - method 3)
17.04 Zinc (cyanide type- total sodium cyanide)
17.05 Zinc (cyanide type- sodium hydroxide - method 1)
17.06 Zinc (cyanide type- sodium hydroxide - method 2)
17.07 Zinc (cyanide type- sodium carbonate)
17.08 Zinc (acid chloride type- zinc - method 1)
17.09 Zinc (acid chloride type- zinc - method 2)
17.10 Zinc (acid chloride type- total chloride - method 1)
17.11 Zinc (acid chloride type- total chloride - method 2)
17.12 Zinc (acid chloride type- boric acid)
17.13 Zinc (alkaline, non-cyanide- zinc)
17.14 Zinc (alkaline, non-cyanide- sodium hydroxide)
18.01 Antimony (fluoride type- antimony)
18.02 Antimony (fluoride type- free hydrofluoric acid)
18.03 Arsenic (cyanide type- arsenic)
18.04 Arsenic (cyanide type- free cyanide)
18.05 Cobalt (sulphate/chloride type)
18.06 Cobalt (sulphate/chloride type-cobalt chloride)
18.07 Cobalt (sulphate/chloride type- boric acid)
18.08 Indium (cyanide type- indium)
18.09 Indium (cyanide type- total cyanide)
18.10 Indium (cyanide type- total hydroxide)
18.11 Indium (acid sulphate type- indium)
18.12 Indium (acid sulphate type- free sulphuric acid)
18.13 Iron (sulphate type- iron)
18.14 Iron (sulphate type- ammonium sulphate)
18.15 Iron (chloride type- iron)
18.16 Iron (chloride type- free hydrochloric acid)
18.17 Iron (chloride type- calcium chloride)
18.18 Palladium (chloride type- palladium - method 1)
18.19 Palladium (chloride type- palladium - method 2)
18.20 Palladium (chloride type- chloride)
18.21 Palladium (chloride type- nitrite)
18.22 Platinum (diamino nitrite type- platinum)
18.23 Platinum (diamino nitrite type- nitrite)
18.24 Platinum (diamino nitrite type- ammonium nitrate)
18.25 Rhodium (sulphate type- rhodium)
18.26 Rhodium (sulphate type- sulphuric acid)
Miscellaneous Solutions
19.01 Cleaners (alkaline- sodium hydroxide, sodium carbonate)
19.02 Cleaners (alkaline- sodium hydroxide, trisodium orthophosphate anhydrous)
19.03 Cleaners (alkaline)- sodium hydroxide, sodium hydroxide concentrations
19.04 Cleaners (alkaline)- sodium carbonate, trisodium ortho-phosphate anhydrous)
19.05 Cleaners (alkaline)- sodium metasilicate
19.06 Cleaners (alkaline)- sodium hydroxide, trisodium ortho-phosphate anhydrous, sodium carbonate
19.07 Etches and pickling solutions (acid- sulphuric acid)
19.08 Etches and pickling solutions (acid- hydrochloric acid)
19.09 Etches and pickling solutions (acid- ortho-phosphoric acid)
19.10 Etches and pickling solutions (acid- nitric acid)
19.11 Stainless steel etching & pickling solutions (HF+HNO 3 acid type)
19.12 Stainless steel etching & pickling solutions (HF+HNO 3 acid type)
19.13 Hydrogen peroxide- concentration
19.14 Sodium hypochlorite- concentration
Standard Volumetric Solutions
20.01 Standardisation of 1.0M hydrochloric acid)
20.02 Standardisation of 1.0M sodium hydroxide)
20.03 Standardisation of 0.1M EDTA)
20.04 Standardisation of 0.1M silver nitrate)
20.05 Standardisation of 0.1M sodium thiosulphate)
20.06 Standardisation of 0.05M Iodine)
20.07 Standardisation of 0.01M thorium nitrate)
20.08 Standardisation of 0.02 potasium permanganate)
20.09 Standardisation of 0.1M ferrous ammonium sulphate
20.10 Standardisation of 0.0167M potassium dichromate - primary standard)
20.11 Standardisation of 0.1M potassium thiocyanate.
20.12 Preparation of 0.05M potassium iodate - primary standard.
Supplementary Methods
S1/01 Phosphating solutions (free ortho-phosphoric acid)
S1/02 Phosphating solutions (iron)
S1/03 Phosphating solutions (calcium)
S1/04 Phosphating solutions (zinc)
S2/01 Yellow passivating solution (zinc - Hexavalent Chromium compounds)
S2/02 Yellow passivating solution (zinc - Trivalent Chromium
S2.03 Blue passivating solution (zinc - hexavalent chromium compounds)
S2/04 Blue passivating solution (zinc trivalent chromium)
S2/05 Black passivating solution (zinc - hexavalent chromium compounds)
S3/01 Copper Electropolishing Solutions (phosphoric acid type - orthophosphoric acid)
S/302 Copper Electropolishing Solutions (phosphoric acid type - copper)
S3/03 Copper Electropolishing Solutions (chromic-phosphoric acid type – chromium trioxide)
S4/01 Copper Chemical Polishing Solutions (chromic-sulphuric acid type - chromium trioxide)
S4/02 Copper Chemical Polishing Solutions (chromic-Sulphuric Acid type - sulphuric acid)
S4/03 Copper Chemical Polishing Solutions (peroxide type - hydrogen peroxide)
S4/04 Copper Chemical Polishing Solutions (peroxide type - copper)
S5/01 Aluminium Electropolishing Solutions (sulphuric-phosphoric acid type - aluminium)
S5/02 Aluminium Electropolishing Solutions (sulphuric-phosphoric type - sulphuric acid, phosphoric acid)
S5/03 Aluminium Electropolishing Solutions (sulphuric-chromic acid type - chromium trioxide)
S5/04 Aluminium Electropolishing Solutions (sulphuric-Chromic Acid type - sulphuric acid)
S5/05 Aluminium Electropolishing Solutions (sulphuric-chromic acid type - aluminium)
S5/06 Aluminium Electropolishing Solutions (fluoboric-boric acid type - fluoboric acid)
S5/07 Aluminium Electropolishing Solutions (fluoboric-boric acid type - aluminium)
S5/08 Aluminium Electropolishing Solutions (fluoboric-boric acid type - boric acid)
S5/09 Aluminium Electropolishing (sodium carbonate phosphate type - sodium carbonate-trisodium ortho-phosphate
S5/10 Aluminium Electropolishing (sodium carbonate phosphate type -aluminium)
S6/01 Aluminium Chemical Polishing Solutions (phosphoric-nitric acid type - nitric acid, ortho-phosphoric acid
S6/02 Aluminium Chemical Polishing Solutions (orthnophosphoric-nitric type - aluminium)
S7/01 Zinc Alloy Processes (zinc-nickel type - zinc)
S7/02 Zinc Alloy Processes (zinc-nickel type - nickel)
S7/03 Zinc Alloy Processes (zinc-nickel type - zinc)
S7/04 Zinc Alloy Processes (zinc-cobalt type - cobalt)


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